9,165 research outputs found
Ab initio analysis of the x-ray absorption spectrum of the myoglobin-carbon monoxide complex: Structure and vibrations
We present a comparison between Fe K-edge x-ray absorption spectra of
carbonmonoxy-myoglobin and its simulation based on density-functional theory
determination of the structure and vibrations and spectral simulation with
multiple-scattering theory. An excellent comparison is obtained for the main
part of the molecular structure without any structural fitting parameters. The
geometry of the CO ligand is reliably determined using a synergic approach to
data analysis. The methodology underlying this approach is expected to be
especially useful in similar situations in which high-resolution data for
structure and vibrations are available.Comment: 13 pages, 3 figure
Cumulant expansion for phonon contributions to the electron spectral function
We describe an approach for calculations of phonon contributions to the
electron spectral function, including both quasiparticle properties and
satellites. The method is based on a cumulant expansion for the retarded
one-electron Green's function and a many-pole model for the electron
self-energy. The electron-phonon couplings are calculated from the Eliashberg
functions, and the phonon density of states is obtained from a Lanczos
representation of the phonon Green's function. Our calculations incorporate ab
initio dynamical matrices and electron-phonon couplings from the density
functional theory code ABINIT. Illustrative results are presented for several
elemental metals and for Einstein and Debye models with a range of coupling
constants. These are compared with experiment and other theoretical models.
Estimates of corrections to Migdal's theorem are obtained by comparing with
leading order contributions to the self-energy, and are found to be significant
only for large electron-phonon couplings at low temperatures
A Multi-Wavelength Study of Sgr A*: The Role of Near-IR Flares in Production of X-ray, Soft -ray and Sub-millimeter Emission
(abridged) We describe highlights of the results of two observing campaigns
in 2004 to investigate the correlation of flare activity in Sgr A* in different
wavelength regimes, using a total of nine ground and space-based telescopes. We
report the detection of several new near-IR flares during the campaign based on
{\it HST} observations. The level of near-IR flare activity can be as low as
mJy at 1.6 m and continuous up to about 40% of the total
observing time. Using the NICMOS instrument on the {\it HST}, the {\it
XMM-Newton} and CSO observatories, we also detect simultaneous bright X-ray and
near-IR flare in which we observe for the first time correlated substructures
as well as simultaneous submillimeter and near-IR flaring. X-ray emission is
arising from the population of near-IR-synchrotron-emitting relativistic
particles which scatter submillimeter seed photons within the inner 10
Schwarzschild radii of Sgr A* up to X-ray energies. In addition, using the
inverse Compton scattering picture, we explain the high energy 20-120 keV
emission from the direction toward Sgr A*, and the lack of one-to-one X-ray
counterparts to near-IR flares, by the variation of the magnetic field and the
spectral index distributions of this population of nonthermal particles. In
this picture, the evidence for the variability of submillimeter emission during
a near-IR flare is produced by the low-energy component of the population of
particles emitting synchrotron near-IR emission. Based on the measurements of
the duration of flares in near-IR and submillimeter wavelengths, we argue that
the cooling could be due to adiabatic expansion with the implication that flare
activity may drive an outflow.Comment: 48 pages, 12 figures, ApJ (in press
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